Different activity at different hour, you will experience the joy of traveling to Thailand.
Morning - Rent a long tail boat (you can share if you found other solo or couple travelers there) and tell them where you want to go. If you are not sure of where to go, let the boatmen guide you.
Afternoon - Maybe one morning is not enough to visit all surrounding nice places. You can have a lunch and continue or even have your lunch at some small islands around. Get back only at evening.
Late afternoon/ Evening - If you come back earlier, just walk from the pier to your hotel. The island is not very tiny in size but there is no motor vehicle available. Rent a bike or travel by foot, walk around and look around. Stop by and buy some local food/snack, they are all tasty.
Evening/Sunset - Go to the beach.
Night - Walking around like shopping in night market. Or, go get some drink and dance!
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