This National Park covers a lot of different areas, which I visited on a few different occasions.
The Izu Peninsula is gorgeous. Many people think you have to go as far as Okinawa to enjoy beautiful crystal clear blue waters and tropical weather, but it's actually found right here in the Izu Islands.
When I went, I took an overnight boat to Kozushima and then camped on the beachside campground. We rented bikes and biked around the island, enjoyed snorkeling, hiking, and BBQs on the beach. It's such a fun thing to do as the summers are longer than back in Tokyo (yet, not far away!).
I also love Hakone so much, I've gone quite a few times and especially love it as a nice weekend getaway from Tokyo. I usually get the package deal with the all-you-can-ride bus/train pass which includes the boat on the lake as well.
If the weather is good, I highly recommend the Open Air Museum - it's one of my favorite museums in the world! And the volcanic area cable cars, too! If it's possible, go during off-season because it can get really crowded otherwise.