I went to Montepulciano a few weeks ago and took some cooking lessons at Scuola di Cucina di Lella in Siena. We had an Italian teacher, very professional and funny lessons and learnt a lot about traditional Tuscan Cuisine and wine tasting.
I know they do speak English very well, and should be exactly what you are looking for.
I've kept their email address: email@example.com
Hope this helps!
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