Great views in this scenic route. You definitely should stop for a picture or a lot at two gorgeous waterfalls (Berlin and Lisbon), God's window, Pinnacle and 3 Rondavells that have stunning views and are really worth the visit. All these places have resting areas where you can stop your car and they also have restrooms and people selling local handcraft. You pay a small fee for each of them (10 - 20 rands).
I wouldn't stop again at Bourke's Luck Potholes. It's overpriced.
You have to pick a day with clear skies in order to enjoy this scenic route.
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