A small nice looking building, in the old Hua Hin style wood construction. But its just a railway station. In a traffic choked corner of the city. Not a tourist attraction.
If you are interested in this type style of building I would recommend taking a half day trip to the Kings old Teak Palace about 10 minutes North of town between Hua Hin and Cha-am. It is really a beautiful building in a a park by the sea with lots of period furniture, silk clothes, sometimes with traditional dance events etc.
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