We satyed in the Hotel Argentina for 3 nights, and had a very nice stay. The hotel is situated right by the Termini Station (2-3 minutes walk, if you come from Fiumiccino you should take the leonardo Express, it's the best way), in a main and busy street but the hotel is quiet.
We only saw receptionists, and they all were very nice. Our room was very comfortable and the shower was renewed so it was very fresh.
As others have said here, when walking on Via Cavour look at all the hotel signs, and you'll find this hotel right by a very nice restaurant, Tudini. Take the (tiny) elevator to the 4th floor and you'll find the reception desk there.
If you're looking for a very central hotel, then you should consider hotels in the Spanish Steps area, but do know that Argentina is only 15 minutes walk from Plaza Espagana and the Spanish Steps. It's also very close the the Historical center and we walked everywhere.
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